This can be done as follows.
[XAML]
<!-- Hard shadow on top of soft shadow. -->
<TextBlock
Text='Shadow Text'
Foreground='CornflowerBlue'>
<TextBlock.BitmapEffect>
<BitmapEffectGroup>
<BitmapEffectGroup.Children>
<DropShadowBitmapEffect
ShadowDepth='5'
Direction='330'
Color='DarkSlateBlue'
Opacity='0.75'
Softness='0.50' />
<DropShadowBitmapEffect
ShadowDepth='2'
Direction='330'
Color='Maroon'
Opacity='0.5'
Softness='0.0' />
</BitmapEffectGroup.Children>
</BitmapEffectGroup>
</TextBlock.BitmapEffect>
</TextBlock>
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