How can I tell if the current row has changed and whether I am on the AddNew row or not
The DataGrid’s CurrentCellChanged event is hit even if you just change cells in the current row. If you want an event that is only hit when you change rows, then you have to look at the binding manager. This object has both a CurrentChanged event and a PositionChanged event which are hit when you change rows.
To decide whether you are on the AddNew row or not, you can again use the binding manager and compare the number of rows it returns with the number of rows in your data table. Below is some code snippets showing how you might get at this information.