Hi Jason,
thank you for your interest in Essential Studio.
It is not possible to insert the new bookmark at the top of any level in the bookmark tree but we can manipulate it, we can insert the new bookmark element at any position ( between bookmarks of similar hierarchy) other than top of every level by using "PdfBookmark.Insert()" function. Please refer the sample in the below location for inserting new bookmarks at specific level.
Sample Link:
http://www.syncfusion.com/uploads/redirect.aspx?&team=support&file=94823-99264482.zipPlease let us know if you have any queries.
Regards,
Angappan.