If you open the document with the Custom Toolbar example in PDF viewer, the exception will be thrown when the second is open.
Error in loading the PDF document
The complete stack is as given below
Syncfusion.Windows.PdfViewer.DocumentToolbar.ResetBackground(ToggleButton currentButton)
Syncfusion.Windows.PdfViewer.DocumentToolbar.Reset()
Syncfusion.Windows.PdfViewer.DocumentView.<Unload>b__6b()
Syncfusion.Windows.PdfViewer.UIDispatcher.Execute(Action action)
Syncfusion.Windows.PdfViewer.DocumentView.Unload()
Syncfusion.Windows.PdfViewer.PdfDocumentView.Unload()
Syncfusion.Windows.PdfViewer.PdfViewerControl.Load(String filePath)