Hi Sai,
Thank you for your interest in Syncfusion Products.
Presently all the bar items are docked to the left on the XPMenus toolbar. There is no provision to either dock it to the right, or to dock some items to the right and left at the same time .You have to use two XPMenus toolBars instead of one. Dock the first XPToolBar on top, and then place the second one over the first at its extreme right. Now anchor the second XPToolBar to top,right. The first XPToolBar can contain the items that are supposed to be on the left side, and the second XPToolBar could contain the rest of the items hat are supposed to be on the right side.
Please refer the sample and let us know if this helps.
http://websamples.syncfusion.com/samples/Tools.Windows/F71127/main.htmRegards,
Jeba.