Hi Keshav,
Thank you for posting query to us.
We can add toolBar to Usercontrol or a Panel. But we can not directly add a toolbar in XPMenu framework to a control. We can workaround this by adding a form having a toolbar to a usercontrol.
Please refer to the attached sample that illustrates the same:
http://websamples.syncfusion.com/samples/Tools.Windows/F68111/main.htmKindly let us know if you need any further assistance.
Thank you for using Syncfusion Products.
Best Regards,
Jeba.