Hi Ryon,
We are really sorry to say that currently we could not change the CaptionBar colors. We already logged feature request in this regard. The feature will be implemented within June 2007.
Here is the feature request link
Feature Request #1243 - Need a provision to set user defined color for captionbar when VisualStyle is OfficeXP/2003/2007 etcDockToFill only works with the overall Form rectangle. We could not change the behavior as you mentioned. It is an internal behavior of DockingManager.
Thanks for using Syncfusion products.
Regards,
Murugan P.S