Hi Alvaro,
Thank you for your update.
We have checked the reported behavior that "MulticolumnCombobox does not seem to be appear in ToolBox in .NET 5.0 " , however we can able to drag and drop the control in designer at our end. Please find the screenshot and sample for the same from following link:
Screenshot:
So please ensure whether all your assemblies are properly referred in your application and whether your toolbox get properly configured at your end. For proper toolbox configuration , please refer the following link:
If you still faces an issue, kindly confirm your product version details and exact scenario that you are facing an issue. It would be helpful for us to check and proceed on it further.
Regards,
Vijayalakshmi VR