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this.grid.Model.Rows.HeaderCount = 1;
this.grid,Model.Rows.FrozenCount = 1;
Then in aPrepareViewStyleInfo event handler, based on the value of e.ColIndex, you could explicitly set the e.Style.Text when e.RowIndex was 0 or 1. To convert e.ColIndex to a letter of the alphabet, you can call the static (Shared in VB) member GridRangeInfo.GetAlphaLabel method.
Here is a little sample to give you the flavor of the kinds of things you can do.
forum11507_4520.zip
else if(e.ColIndex == 0 && e.RowIndex > 0)
{
e.Style.CellType = "Header";
e.Style.Text = e.RowIndex.ToString();
e.Style.Font.Bold = false;
}